Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel)

Shubhangi S. Nigade; Sangram D. Jadhav; Abhimanyu K. Chandgude

doi:doi:10.11648/j.ijepe.s.2015040501.18

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Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel)

Shubhangi S. Nigade, Sangram D. Jadhav, Abhimanyu K. Chandgude

Published in International Journal of Energy and Power Engineering (Volume 4, Issue 5-1)

Received: 27 March 2015 Accepted: 28 May 2015 Published: 2 September 2015

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Abstract

The depletion of resources, increased cost of fossil fuel and increased environmental awareness reaching the critical condition. Development of viable alternative fuels from renewable resources is gaining the international attention and acceptance. The vegetable oils have the potential of alternative fuel for compression ignition engines by converting it into biodiesel. The mangifera indica oil is a nonedible vegetable oil, available in large quantities in mangifera indica cultivating countries including India. Very little research has been done on utilization of oil in general and optimization of transesterification process for biodiesel production. However, direct base catalyzed transesterification produced no biodiesel due to the high Free Fatty Acid ( FFA) value of the oil. Hence, acid pretreatment was preferred prior to base transesterification which afforded a significant reduction of the FFA value from 3.3% to 0.9% . Various input parameters like oil-to-methanol molar ratio (1:08, 1:12 and 1:16), catalyst type (NaOH, KOH and NaOCH3), catalyst concentration (0.5, 1 and 1.5 wt %) and reaction temperature (59, 64 and 69°C) were studied. The optimum conditions for transesterification process are: 1:12 oil-to-methanol molar ratio, 1.0 wt.% catalyst concentration, KOH catalyst, & 64°C reaction temperature. The optimum yield of MOME was 89.8%. The biodiesel produced (MOME) is within the limits prescribed by EN-14214 standard.

Published in	International Journal of Energy and Power Engineering (Volume 4, Issue 5-1) This article belongs to the Special Issue Energy Systems and Developments
DOI	10.11648/j.ijepe.s.2015040501.18
Page(s)	48-53
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Biodiesel, Extraction, Mangifera Indica, Pretreatment, Transesterification

References

[1]	Abbaszaadeh Ahmad, Barat Ghobadian, Mohammad Reza Omidkhah, and Gholamhassan Najafi. 2012. “Current Biodiesel Production Technologies: A Comparative Review.” Energy Conversion and Management 63:138–48.
[2]	Bagby M, and B Freedman. 1987. “Preparation and Properties from Vegetable Oils” 66: 1372–78.
[3]	Balat Mustafa, and Havva Balat. 2010. “Progress in Biodiesel Processing.” Applied Energy 87 (6): 1815–35.
[4]	Dorado M.P., Ballesteros, E., Almeida, J.A., Schellert, C., Lohrlein, H.P. and Krause, R., "An alkali-catalyzed transesterification process for high free fatty acid waste oils". ASAE 45(2002) 525-29.
[5]	Barnwal B.K., and M.P. Sharma. 2005. “Prospects of Biodiesel Production from Vegetable Oils in India.” Renewable and Sustainable Energy Reviews 9 (4): 363–78.
[6]	Tapasvi D., Wisenborn D. and Gustafson C., "Process model for biodiesel production from various feedstocks". ASAE, 48 (2005) 2215-21
[7]	Bozbas Kahraman. 2008. “Biodiesel as an Alternative Motor Fuel: Production and Policies in the European Union.” Renewable and Sustainable Energy Reviews 12 (2): 542–52.
[8]	“BP Statistical Review of World Energy June 2012, 2013, 2014. 68th edition.
[9]	Government of India Planning Commission, 2011. “Faster , Sustainable and More Inclusive Growth An Approach to the Twelfth five year plan 2012-17 .”
[10]	Demirbas Ayhan. 2009. “Progress and Recent Trends in Biodiesel Fuels.” Energy Conversion and Management 50 (1): 14–34.
[11]	Formo Marvin W, and Archer-daniels-midland Company. 1953. “Ester Reactions of Fatty Materials” 31 (130): 548–59.
[12]	Fukuda Hidekl, Akihiko Kond, and Hide Noda. 2001. “Biodiesel Fuel Production by Transesterification” 92 (5) 405-416.
[13]	Haas Michael J, Andrew J McAloon, Winnie C Yee, and Thomas a Foglia. 2006. “A Process Model to Estimate Biodiesel Production Costs.” Bioresource Technology 97 (4): 671–78.
[14]	Jadhav Sangram D, and Madhukar S Tandale. 2014. “Production, Performance and Emission Study of Mahua (Madhuca Indica) Methyl Ester in Multicylinder 4-Stroke Petrol Engine” 3 (1): 2582–86.
[15]	Karaosmanog Filiz. 2004. “Optimization of Base-Catalyzed Transesterification” 5 (2): 1888–95.
[16]	W. Kdrbltz, 1999. “Biodiesel production in Europe and North America, An Encourging prospects” Renewable Energy 16, 1078–83.
[17]	Knothe Gerhard. 2005. “Dependence of Biodiesel Fuel Properties on the Structure of Fatty Acid Alkyl Esters” 86: 1059–70.
[18]	Marchetti J M A, V U Miguel, and A F Errazu. 2007. “Possible Methods for Biodiesel Production” 11: 1300–1311.
[19]	Meher L, D Vidyasagar, and S Naik. 2006. “Technical Aspects of Biodiesel Production by Transesterification—a Review.” Renewable and Sustainable Energy Reviews 10 (3): 248–68.
[20]	S. S. Raju, R. Chand, P. Kumar, and Siwa Msangi. 2012. “ Biofuels in India: Potential , Policy and Emerging Paradigms.”NCAP New Delhi 14: 1–18.
[21]	Olutoye M a, and B H Hameed. 2013. “Production of Biodiesel Fuel by Transesterification of Different Vegetable Oils with Methanol Using Al2O3 Modified MgZnO Catalyst.” Bioresource Technology 132: 103–8.
[22]	Pinzi S., I. L. Garcia, F. J. Lopez-Gimenez, M. D. Luque de Castro, G. Dorado, and M. P. Dorado. 2009. “The Ideal Vegetable Oil-Based Biodiesel Composition: A Review of Social, Economical and Technical Implications.” Energy & Fuels 23 (5): 2325–41.
[23]	Saravanan N., Sukumar Puhan, G. Nagarajan, and N. Vedaraman. 2010. “An Experimental Comparison of Transesterification Process with Different Alcohols Using Acid Catalysts.” Biomass and Bioenergy 34 (7): 999–1005.
[24]	Sharma Y C, and B Singh. 2009. “Development of Biodiesel : Current Scenario” 13: 1646–51.
[25]	Shay E.Griffin. 1993. “Diesel Fuel from Vegetable Oils: Status and Opportunities.” Biomass and Bioenergy 4 (4): 227–42.
[26]	Shiu Pei-jing, Setiyo Gunawan, Wen-hao Hsieh, Novy S Kasim, and Yi-hsu Ju. 2010. “Bioresource Technology Biodiesel Production from Rice Bran by a Two-Step in-Situ Process.” Bioresource Technology 101 (3): 984–89.
[27]	Srivastava Anjana, and Ram Prasad. 2000. “Triglycerides-Based Diesel Fuels.” Renewable and Sustainable Energy Reviews 4 (2): 111–33.
[28]	Thammarat Nakhon et al. 2013. “Mangifera indica Seed Kernel Oil and Its Physicochemical Properties” 20 (3): 1145–49.
[29]	Tu Le, Kenji Okitsu, Yasuhiro Sadanaga, Norimichi Takenaka, and Yasuaki Maeda. 2010. “Bioresource Technology A Two-Step Continuous Ultrasound Assisted Production of Biodiesel Fuel from Waste Cooking Oils: A Practical and Economical Approach to Produce High Quality Biodiesel Fuel.” Bioresource Technology 101 (14): 5394–5401.
[30]	“Statistical Division Food and Agricultural Organisation of United Nations: Economic and social Department. UN Food and Agricultural Organisation Corporate statistical Database 2011-12.”
[31]	Zelenka Paul, Wolfgang Cartellieri, and Peter Herzog. 1996. “Worldwide Diesel Emission Standards , Current Experiences and Future Needs” 10: 3–28.

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Shubhangi S. Nigade, Sangram D. Jadhav, Abhimanyu K. Chandgude. (2015). Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel). International Journal of Energy and Power Engineering, 4(5-1), 48-53. https://doi.org/10.11648/j.ijepe.s.2015040501.18

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ACS Style

Shubhangi S. Nigade; Sangram D. Jadhav; Abhimanyu K. Chandgude. Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel). Int. J. Energy Power Eng. 2015, 4(5-1), 48-53. doi: 10.11648/j.ijepe.s.2015040501.18

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AMA Style

Shubhangi S. Nigade, Sangram D. Jadhav, Abhimanyu K. Chandgude. Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel). Int J Energy Power Eng. 2015;4(5-1):48-53. doi: 10.11648/j.ijepe.s.2015040501.18

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@article{10.11648/j.ijepe.s.2015040501.18,
  author = {Shubhangi S. Nigade and Sangram D. Jadhav and Abhimanyu K. Chandgude},
  title = {Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel)},
  journal = {International Journal of Energy and Power Engineering},
  volume = {4},
  number = {5-1},
  pages = {48-53},
  doi = {10.11648/j.ijepe.s.2015040501.18},
  url = {https://doi.org/10.11648/j.ijepe.s.2015040501.18},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepe.s.2015040501.18},
  abstract = {The depletion of resources, increased cost of fossil fuel and increased environmental awareness reaching the critical condition. Development of viable alternative fuels from renewable resources is gaining the international attention and acceptance. The vegetable oils have the potential of alternative fuel for compression ignition engines by converting it into biodiesel. The mangifera indica oil is a nonedible vegetable oil, available in large quantities in mangifera indica cultivating countries including India. Very little research has been done on utilization of oil in general and optimization of transesterification process for biodiesel production. However, direct base catalyzed transesterification produced no biodiesel due to the high Free Fatty Acid ( FFA) value of the oil. Hence, acid pretreatment was preferred prior to base transesterification which afforded a significant reduction of the FFA value from 3.3% to 0.9% . Various input parameters like oil-to-methanol molar ratio (1:08, 1:12 and 1:16), catalyst type (NaOH, KOH and NaOCH3), catalyst concentration (0.5, 1 and 1.5 wt %) and reaction temperature (59, 64 and 69°C) were studied. The optimum conditions for transesterification process are: 1:12 oil-to-methanol molar ratio, 1.0 wt.% catalyst concentration, KOH catalyst, & 64°C reaction temperature. The optimum yield of MOME was 89.8%. The biodiesel produced (MOME) is within the limits prescribed by EN-14214 standard.},
 year = {2015}
}

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TY - JOUR
T1 - Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel)
AU - Shubhangi S. Nigade
AU - Sangram D. Jadhav
AU - Abhimanyu K. Chandgude
Y1 - 2015/09/02
PY - 2015
N1 - https://doi.org/10.11648/j.ijepe.s.2015040501.18
DO - 10.11648/j.ijepe.s.2015040501.18
T2 - International Journal of Energy and Power Engineering
JF - International Journal of Energy and Power Engineering
JO - International Journal of Energy and Power Engineering
SP - 48
EP - 53
PB - Science Publishing Group
SN - 2326-960X
UR - https://doi.org/10.11648/j.ijepe.s.2015040501.18
AB - The depletion of resources, increased cost of fossil fuel and increased environmental awareness reaching the critical condition. Development of viable alternative fuels from renewable resources is gaining the international attention and acceptance. The vegetable oils have the potential of alternative fuel for compression ignition engines by converting it into biodiesel. The mangifera indica oil is a nonedible vegetable oil, available in large quantities in mangifera indica cultivating countries including India. Very little research has been done on utilization of oil in general and optimization of transesterification process for biodiesel production. However, direct base catalyzed transesterification produced no biodiesel due to the high Free Fatty Acid ( FFA) value of the oil. Hence, acid pretreatment was preferred prior to base transesterification which afforded a significant reduction of the FFA value from 3.3% to 0.9% . Various input parameters like oil-to-methanol molar ratio (1:08, 1:12 and 1:16), catalyst type (NaOH, KOH and NaOCH3), catalyst concentration (0.5, 1 and 1.5 wt %) and reaction temperature (59, 64 and 69°C) were studied. The optimum conditions for transesterification process are: 1:12 oil-to-methanol molar ratio, 1.0 wt.% catalyst concentration, KOH catalyst, & 64°C reaction temperature. The optimum yield of MOME was 89.8%. The biodiesel produced (MOME) is within the limits prescribed by EN-14214 standard.
VL - 4
IS - 5-1
ER -

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Author Information

Shubhangi S. Nigade

Department of Mechanical Engineering, KJEI’s Trinity college of Engineering and Research Pune, Maharashtra, India
Sangram D. Jadhav

Department of Mechanical Engineering, Government of Maharashtra Dr. B. A. Technological University Mangaon, Maharashtra, India
Abhimanyu K. Chandgude

Department of Mechanical Engineering, KJEI’s Trinity college of Engineering and Research Pune, Maharashtra, India

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APA Style

Shubhangi S. Nigade, Sangram D. Jadhav, Abhimanyu K. Chandgude. (2015). Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel). International Journal of Energy and Power Engineering, 4(5-1), 48-53. https://doi.org/10.11648/j.ijepe.s.2015040501.18

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ACS Style

Shubhangi S. Nigade; Sangram D. Jadhav; Abhimanyu K. Chandgude. Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel). Int. J. Energy Power Eng. 2015, 4(5-1), 48-53. doi: 10.11648/j.ijepe.s.2015040501.18

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AMA Style

Shubhangi S. Nigade, Sangram D. Jadhav, Abhimanyu K. Chandgude. Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel). Int J Energy Power Eng. 2015;4(5-1):48-53. doi: 10.11648/j.ijepe.s.2015040501.18

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@article{10.11648/j.ijepe.s.2015040501.18,
  author = {Shubhangi S. Nigade and Sangram D. Jadhav and Abhimanyu K. Chandgude},
  title = {Development of Transesterification System with Acid and Base Homogeneous Catalysts For Mangifera Indica Seed Oil to Mangifera Indica Methyl Ester (MOME Biodiesel)},
  journal = {International Journal of Energy and Power Engineering},
  volume = {4},
  number = {5-1},
  pages = {48-53},
  doi = {10.11648/j.ijepe.s.2015040501.18},
  url = {https://doi.org/10.11648/j.ijepe.s.2015040501.18},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepe.s.2015040501.18},
  abstract = {The depletion of resources, increased cost of fossil fuel and increased environmental awareness reaching the critical condition. Development of viable alternative fuels from renewable resources is gaining the international attention and acceptance. The vegetable oils have the potential of alternative fuel for compression ignition engines by converting it into biodiesel. The mangifera indica oil is a nonedible vegetable oil, available in large quantities in mangifera indica cultivating countries including India. Very little research has been done on utilization of oil in general and optimization of transesterification process for biodiesel production. However, direct base catalyzed transesterification produced no biodiesel due to the high Free Fatty Acid ( FFA) value of the oil. Hence, acid pretreatment was preferred prior to base transesterification which afforded a significant reduction of the FFA value from 3.3% to 0.9% . Various input parameters like oil-to-methanol molar ratio (1:08, 1:12 and 1:16), catalyst type (NaOH, KOH and NaOCH3), catalyst concentration (0.5, 1 and 1.5 wt %) and reaction temperature (59, 64 and 69°C) were studied. The optimum conditions for transesterification process are: 1:12 oil-to-methanol molar ratio, 1.0 wt.% catalyst concentration, KOH catalyst, & 64°C reaction temperature. The optimum yield of MOME was 89.8%. The biodiesel produced (MOME) is within the limits prescribed by EN-14214 standard.},
 year = {2015}
}

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