Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline

Naciye Türkel

doi:doi:10.11648/j.sjc.20130102.12

| Peer-Reviewed

Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline

Naciye Türkel

Published in Science Journal of Chemistry (Volume 1, Issue 2)

Received: 16 May 2013 Published: 20 June 2013

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.

Published in	Science Journal of Chemistry (Volume 1, Issue 2)
DOI	10.11648/j.sjc.20130102.12
Page(s)	21-25
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Stability constants, 8-Hydroxyquinoline, Sc(III), Y(III), La(III)

References

[1]	N. N. Greenwood, A. Earnshaw, Chemistry of the elements, second edition, Elsevier Butterworth Heinemann, 1997.
[2]	G. A. Melson, R. W. Stotz, Coord. Chem. Rev. 7 (1971) 133e160.
[3]	J. A. Mc Cleverty, A. Specialist periodical reports inorganic chemistry of transition elements; vol. 4, Library of Congress catalog no.72-83458, The marketing officer, The Chemical Society Burlington House, London W1V OBN, 1976.
[4]	U. Özer, Chimica Acta Turcica 13 (1985) 253e270.
[5]	N. Türkel, U. Özer, Chem. Pharm. Bull. 48, 6 (2000) 870e872.
[6]	N. Türkel, U. Özer, Russian Journal of Coordination Chemistry 31, 3 (2005) 213e217.
[7]	N. Türkel, Asian J. Chem. 18, 3 (2006) 1978e1986.
[8]	N. Türkel, J. Chem. Eng. Data 56 (2011) 2337e2342.
[9]	K. Arora and K. Burman, Reviews in Inorganic Chemistry 29, 2 (2009) 83e101.
[10]	J. Hala, J. Inorg. Nucl. Chem. 27 (1965) 2659e2664.
[11]	L.M. Ramenskaya, O. V. Kraeva, Russian Journal of Physical Chemistry 80, 1 (2006) 90e94.
[12]	S. C. Lee, R. M. Izatt, X. X. Zhang, E. G. Nelson, J. D. Lamb, P. B. Savage, J. S. Bradshaw, Inorg. Chim. Acta 317 (2001) 174e180.
[13]	J. P. Philips, Chem. Rev. 95 (1956) 271e297.
[14]	C. F. Richard, R. L. Gustafson, A. E. Martell, J. Am. Chem. Soc. March 5, 81 (1959) 1033e1040.
[15]	J. T. Spence, E. R. Peterson, Inorg. Chem. 1, 2 (1962) 277e280.
[16]	M. R. Chakrabarty, E. S. Hanrahan, N. D. Heindel, G. F. Watts, Anal. Chem. 39 (1967) 238e241.
[17]	M. P. Bratzel, J. J. Aaron, J. D Winefordner, S. G. Schulman, H. Gershon, Anal. Chem. 44 (1972) 1240e1245.
[18]	S. E. Pattison, M. F. Dunn, Biochemistry 15,17 (1976) 3691e3696.
[19]	Z. Zhujun, W. R. Seitz, Anal. Chim. Acta, 171 (1985) 251e258.
[20]	K. Soroka, R. S. Vithanage, D. A. Philips, B. Walker, P. K. Dasgupta, Anal. Chem. 59 (1987) 629e636.
[21]	M. Yamato, K. Hashigaki, Y. Yasumoto, J. Sakai, R. F. Luduena, A. Banerjee, S. Tsukagoshi, T. Tashiro, T. Tsuruo, J. Med. Chem. 30 (1987) 1897e1900.
[22]	Z. Yang, J. S. Bradshaw, X. X. Zhang, P. B. Savage, K. E. Krakowaik, N. K. Dalley, N.Su, R. T. Bronson, R. M. Izatt, J. Org. Chem. 64 (1999) 3162e3170.
[23]	M. Borrel, R. A. Paris, Analytica Chimica Acta 6 (1952) 389e399.
[24]	P. Singh, S. Kumar, Tetrahedron Letters 47 (2006) 109e112.
[25]	D. Badocco, A. Dean, V. D. Marco, P. Pastore, Electrochimica Acta 52 (2007) 7920e7926.
[26]	R. Nasanen, Acta Chem Scand. 5 (1951) 1293e1300.
[27]	R. Nasanen, Acta Chem Scand. 6 (1952) 352e357.
[28]	J. Stary, Yu. A. Zolotov, O. M. Petrukhin, Critical evaluation of equilibrium constant involving 8-hydroxyquinoline and its metal chelates.Pergaman Pres, Oxford, 1979
[29]	D. Dyrssen, V. Dahlberg, Acta Chem. Scand. 7, 8 (1953) 1186e1196.
[30]	W. D. Johnston, H. Freiser, Journal of the American Chemical Society 74, November 5 (1952) 5239e5242.
[31]	A.E. Martell, R. M. Smith, R.J. Motekaitis, NIST Critically selected stability constants of metal complexes database 46, version 4.0, NIST, Gaithersburg, MD, 1997.
[32]	B. Magyar, P. Wechsler, Talanta 23, 2 (1976) 95e101.
[33]	D. C. Sulıkowska, N. Pustelnik, Chemia Analityczna 37 (1992) 265e272.
[34]	A. T. Rane, J. Inorg. Nucl. Chem. 42 (1980) 1520e1521.
[35]	T. Yu. Matrosovich, F. I. Lobanov, N. V. Markarov, Russian Journal of Inorganic Chemistry 31, 6 (1986) 823e827.
[36]	J. Rydberg, Acta Chemica Scandinavica 14 (1960) 157e179.
[37]	A. E. Martell, R. J. Motekaitis, Determination and Use of Stability Constants; VCH Publishers:New York, NY, USA, 1989.
[38]	G. Schwarzenbach, H. Flaschka, H. Complexometric titrations; Interscience: New York, NY, USA, 1969.
[39]	G. Gran, Analyst 77 (1952) 661e771.

Cite This Article

Plain Text BibTeX RIS

APA Style

Naciye Türkel. (2013). Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Science Journal of Chemistry, 1(2), 21-25. https://doi.org/10.11648/j.sjc.20130102.12

Copy | Download

ACS Style

Naciye Türkel. Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Sci. J. Chem. 2013, 1(2), 21-25. doi: 10.11648/j.sjc.20130102.12

Copy | Download

AMA Style

Naciye Türkel. Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Sci J Chem. 2013;1(2):21-25. doi: 10.11648/j.sjc.20130102.12

Copy | Download

@article{10.11648/j.sjc.20130102.12,
  author = {Naciye Türkel},
  title = {Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {2},
  pages = {21-25},
  doi = {10.11648/j.sjc.20130102.12},
  url = {https://doi.org/10.11648/j.sjc.20130102.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130102.12},
  abstract = {This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline
AU  - Naciye Türkel
Y1  - 2013/06/20
PY  - 2013
N1  - https://doi.org/10.11648/j.sjc.20130102.12
DO  - 10.11648/j.sjc.20130102.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 21
EP  - 25
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130102.12
AB  - This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.
VL  - 1
IS  - 2
ER  -

Copy | Download

Author Information

Naciye Türkel

Uluda? University, Faculty of Arts and Sciences, Department of Chemistry, 16059-Bursa, Turkey

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Naciye Türkel. (2013). Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Science Journal of Chemistry, 1(2), 21-25. https://doi.org/10.11648/j.sjc.20130102.12

Copy | Download

ACS Style

Naciye Türkel. Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Sci. J. Chem. 2013, 1(2), 21-25. doi: 10.11648/j.sjc.20130102.12

Copy | Download

AMA Style

Naciye Türkel. Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline. Sci J Chem. 2013;1(2):21-25. doi: 10.11648/j.sjc.20130102.12

Copy | Download

@article{10.11648/j.sjc.20130102.12,
  author = {Naciye Türkel},
  title = {Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {2},
  pages = {21-25},
  doi = {10.11648/j.sjc.20130102.12},
  url = {https://doi.org/10.11648/j.sjc.20130102.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130102.12},
  abstract = {This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Complex Formation Reactions of Scandium(III), Yttrium(III) and Lanthanum(III) Complexes with 8-Hydroxyquinoline
AU  - Naciye Türkel
Y1  - 2013/06/20
PY  - 2013
N1  - https://doi.org/10.11648/j.sjc.20130102.12
DO  - 10.11648/j.sjc.20130102.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 21
EP  - 25
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130102.12
AB  - This study aims to investigate the nature and types of complexes formed in aqueous solution between 8-Hydroxyquinoline (HQ) and the ions of Sc+3, Y+3, and La+3. Potentiometric titration was used to follow the formation of complexes. The coordination compounds formed were studied through the determination of stability constants of these complexes in aqueous solution at 25,0 ± 0,1ºC and ionic strength of 0,1 M KNO3. The basicity of the ligand was also assessed by the determination of the dissociation constants of the ligand. All of the constants were determined by computer refinement of pH-volume data using the BEST computer program. Distribution diagrams for the species were drawn showing the concentrations of individual species as a function of pH by the SPE software program.
VL  - 1
IS  - 2
ER  -

Copy | Download