The paper reports a study on phosphate glasses containing Chromium, Iron and Sodium oxides. The phosphate glasses have been obtained in air by direct melting of Cr2O3, Fe2O3, Na2CO3, and (NH4)2HPO4. The preparation temperature is 1020°C. After annealing at 650°C for 48h, the glasses were partially crystallized and contained β-CrPO4 and Fe3(P2O7)2 crystalline phases. We have performed the measurement of X-Ray diffraction, and Infra-Infra-Red spectroscopy. The differential scanning calorimetry (DSC) was used in this work to determine the glass transition and the crystallization temperatures (Tg and Tc). We noticed that the Tg and Tc depends on the composition of the samples. The chemical durability was evaluated by weight losses of glass samples after immersion in hot distilled water at 90°C for 30 days. Weight loss measurements showed a good chemical durability against water and enhance the glass capacity to embed different chemical compounds. The density and molar volume were also measured.
| Published in |
International Journal of Materials Science and Applications (Volume 7, Issue 1-1)
This article belongs to the Special Issue Energy and Materials II |
| DOI | 10.11648/j.ijmsa.s.2018070101.13 |
| Page(s) | 11-17 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2017. Published by Science Publishing Group |
Chemical Durability, IR Spectroscopy, Differential Scanning Calorimetry, Glass Formation, Sodium-Chromium-Iron-Phosphate Glasses, XRD
| [1] | B. C. Sales, M. M. Abraham, J. B. Bates and L. A. Boat- ner, “Structural Properties of Lead-Iron Phosphate Glass- es,” Journal of Non-Crystalline, Vol. 71, 1985, pp. 103- 112. http://dx.doi.org/10.1016/0022-3093(85)90279-0 |
| [2] | B. C. Sales and L. A. Boatner, “Physical and Chemical Characteristics of Lead-Iron Phosphate Nuclear Waste Glasses,” Journal of Non-Crystalline Solids, Vol. 79, 1986, pp. 83-116. http://dx.doi.org/10.1016/0022-3093(86)90040-2 |
| [3] | X. Yu, D. E. Day, G. J. Long, R. K. Brow, J. Non-Cryst. Solids 215 (1997) 21. |
| [4] | R. K. Brow, C. M. Arens, X. Yu, D. E. Day, Phys. Chem. Glasses 35 (1994) 132. |
| [5] | Y. Makhkhas, S. Aqdim, E. H. Sayouty “Study of Sodium-Chromium-Iron-Phosphate Glass by XRD, IR, Chemical Durability and SEM” Journal of Materials Science and Chemical Engineering 2013, 1, 1-6. |
| [6] | R. K. Brow, J. Non-Crist. Solids 263&264(2000) 1. |
| [7] | J. Clement, J. M. Manero. J. A. Panell, G. Avila, S. Martinez, J. Mater. Sci. Mater. Med. 10(1999) 729. |
| [8] | Y. Makhkhas and E. H. Sayouty “CHEMICAL DURABILITY AND CHARACTERIZATION OF THE PHOSPHATE GLASSES CONTAINING IRON, SODIUM AND CHROMIUM” International Journal of Advances in Chemistry (IJAC) Vol. 2, No. 1, 23-29. |
| [9] | D. E. Day, Z. Wu, C. S. Ray, P. Hrma, J. Non-Cryst. Solids 241 (1998) 1. |
| [10] | T. Yamashita, S. Hayashi, M. Yoshida, Method for manufacturing precision glass spheres and method for manufacturing optical glass elements, 2005 (Patent Nos. JP2005272292, US2005210923). |
| [11] | N. Kopylov, A. Kortan, Method for manufacturing phosphate glass-coated fluoride glass optical fibers, 1999 (Patent No. US5858052). |
| [12] | J. Iseki, H. Higata, T. Yamanaka, Glass for sealing and sealing material which uses it, 2002 (Patent No. JP2002037644). |
| [13] | T. Ishidoya, Y. Minoura, Dosimeter glass element method for manufacturing same and dosimeter holder, 2003 (Patent Nos. JP2003073137, US2003071229). |
| [14] | E. Daniela, D. Cacaina, M. Coldea, M. Valeanu, S. Simon, J. Magn. Magn. Mater. 293 (2005) 310. |
| [15] | E. A. Lisitsyna, V. D. Khalilev, S. P. Lunkin, Glass for heat-shielding lightfilters, 1987 (Patent No. SU1291562). |
| [16] | L. Montagne, G. Palavit, R. Delaval, «Effect of ZnO on properties of (100-x)(NaPO3) – x ZnO glasses », J. Non Cryst. Solids, 223 (1998) 43. |
| [17] | F. Delahaye-Carrière «Influence de la solution altérante sur la dissolution des verres du système (50-x)Na2O-xCaO-50P2O5» Thèse de l'Université de Technologie de Compiègne-Lille. 1997. |
| [18] | K. Nakamoto, in: Infrared spectra of Inorganic and Coordination Compounds, Wiley-Interscience, New York, 1970. |
| [19] | Y. M. Moustafa, A. EL-Adawy, Phys. Stat. Sol. (a) 179 (2000) 83. |
| [20] | D. E. C. Corbridge, E. J. Low, J. Chem. Soc. Part I (1954) 493. |
| [21] | S. Krimi, I. Mansouri, A. El Jazouli, J. P. Chaminade, P. Gravereau, G. Le Flem, J. Solid State Chem. 105 (1993) 561–566. |
APA Style
Youssef Makhkhas, Saida Krimi, Mohamed Taibi, El Hassan Sayouty. (2017). Preparation and Characterization of Phosphate Material Doped with Chromium. International Journal of Materials Science and Applications, 7(1-1), 11-17. https://doi.org/10.11648/j.ijmsa.s.2018070101.13
ACS Style
Youssef Makhkhas; Saida Krimi; Mohamed Taibi; El Hassan Sayouty. Preparation and Characterization of Phosphate Material Doped with Chromium. Int. J. Mater. Sci. Appl. 2017, 7(1-1), 11-17. doi: 10.11648/j.ijmsa.s.2018070101.13
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Download@article{10.11648/j.ijmsa.s.2018070101.13,
author = {Youssef Makhkhas and Saida Krimi and Mohamed Taibi and El Hassan Sayouty},
title = {Preparation and Characterization of Phosphate Material Doped with Chromium},
journal = {International Journal of Materials Science and Applications},
volume = {7},
number = {1-1},
pages = {11-17},
doi = {10.11648/j.ijmsa.s.2018070101.13},
url = {https://doi.org/10.11648/j.ijmsa.s.2018070101.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.s.2018070101.13},
abstract = {The paper reports a study on phosphate glasses containing Chromium, Iron and Sodium oxides. The phosphate glasses have been obtained in air by direct melting of Cr2O3, Fe2O3, Na2CO3, and (NH4)2HPO4. The preparation temperature is 1020°C. After annealing at 650°C for 48h, the glasses were partially crystallized and contained β-CrPO4 and Fe3(P2O7)2 crystalline phases. We have performed the measurement of X-Ray diffraction, and Infra-Infra-Red spectroscopy. The differential scanning calorimetry (DSC) was used in this work to determine the glass transition and the crystallization temperatures (Tg and Tc). We noticed that the Tg and Tc depends on the composition of the samples. The chemical durability was evaluated by weight losses of glass samples after immersion in hot distilled water at 90°C for 30 days. Weight loss measurements showed a good chemical durability against water and enhance the glass capacity to embed different chemical compounds. The density and molar volume were also measured.},
year = {2017}
}
TY - JOUR T1 - Preparation and Characterization of Phosphate Material Doped with Chromium AU - Youssef Makhkhas AU - Saida Krimi AU - Mohamed Taibi AU - El Hassan Sayouty Y1 - 2017/11/07 PY - 2017 N1 - https://doi.org/10.11648/j.ijmsa.s.2018070101.13 DO - 10.11648/j.ijmsa.s.2018070101.13 T2 - International Journal of Materials Science and Applications JF - International Journal of Materials Science and Applications JO - International Journal of Materials Science and Applications SP - 11 EP - 17 PB - Science Publishing Group SN - 2327-2643 UR - https://doi.org/10.11648/j.ijmsa.s.2018070101.13 AB - The paper reports a study on phosphate glasses containing Chromium, Iron and Sodium oxides. The phosphate glasses have been obtained in air by direct melting of Cr2O3, Fe2O3, Na2CO3, and (NH4)2HPO4. The preparation temperature is 1020°C. After annealing at 650°C for 48h, the glasses were partially crystallized and contained β-CrPO4 and Fe3(P2O7)2 crystalline phases. We have performed the measurement of X-Ray diffraction, and Infra-Infra-Red spectroscopy. The differential scanning calorimetry (DSC) was used in this work to determine the glass transition and the crystallization temperatures (Tg and Tc). We noticed that the Tg and Tc depends on the composition of the samples. The chemical durability was evaluated by weight losses of glass samples after immersion in hot distilled water at 90°C for 30 days. Weight loss measurements showed a good chemical durability against water and enhance the glass capacity to embed different chemical compounds. The density and molar volume were also measured. VL - 7 IS - 1-1 ER -
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